Potassium Cyanide - Structure

Structure

In aqueous solution, KCN is dissociated into hydrated K+ ions and CN−. As a solid, the salt crystallizes such that the cations and anions organize like Na+ and Cl− in NaCl. The cations and anions six-coordinate. Each K+ is linked to two pi-bonds of the CN− as well as two links each to C and N each. Since CN− is diatomic, the symmetry of the solid is lower than that in NaCl. The cyanide anions form sheets. The CN− ions rapidly rotate in the solid at ambient temperature such that the time averaged shape of the CN− ions is spherical.

Read more about this topic:  Potassium Cyanide

Famous quotes containing the word structure:

    The verbal poetical texture of Shakespeare is the greatest the world has known, and is immensely superior to the structure of his plays as plays. With Shakespeare it is the metaphor that is the thing, not the play.
    Vladimir Nabokov (1899–1977)

    ... the structure of our public morality crashed to earth. Above its grave a tombstone read, “Be tolerant—even of evil.” Logically the next step would be to say to our commonwealth’s criminals, “I disagree that it’s all right to rob and murder, but naturally I respect your opinion.” Tolerance is only complacence when it makes no distinction between right and wrong.
    Sarah Patton Boyle, U.S. civil rights activist and author. The Desegregated Heart, part 2, ch. 2 (1962)

    Why does philosophy use concepts and why does faith use symbols if both try to express the same ultimate? The answer, of course, is that the relation to the ultimate is not the same in each case. The philosophical relation is in principle a detached description of the basic structure in which the ultimate manifests itself. The relation of faith is in principle an involved expression of concern about the meaning of the ultimate for the faithful.
    Paul Tillich (1886–1965)