Polyoxometalate - Structure

Structure

Some structural types are found in many different compounds. The first known example of this was the Keggin ion, whose structure was found to be common to both molybdates and tungstates with different central hetero atoms. Examples of some fundamental polyoxometalate structures are shown below. The Lindqvist ion is an iso-polyoxometalate, the other three are hetero-polyoxometalates. The Keggin and Dawson structures have tetrahedrally coordinated hetero-atoms, such as P or Si, and the Anderson structure has an octahedral central atom, such as aluminium.

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