Polyhedral Skeletal Electron Pair Theory

In chemistry the polyhedral skeletal electron pair theory provides electron counting rules useful for predicting the structures of clusters such as borane and carborane clusters. The electron counting rules were originally formulated by Kenneth Wade and were further developed by D. M. P. Mingos and others; they are sometimes known as Wade's rules or the Wade/Mingos rules. The rules are based on a molecular orbital treatment of the bonding. These rules have been extended and unified in the form of the Jemmis mno rules.