Polyaniline - History

History

As described by MacDiarmid, the first definitive report of polyaniline did not occur until 1862, which included an electrochemical method for the determination of small quantities of aniline.

From the early 20th century on, occasional reports about the structure of PANI were published. Subsequent to his investigation of other highly-conductive organic materials, MacDiarmid demonstrated the conductive states of polyaniline which arose upon protonic doping of the emeradine form of polyaniline. Conductive polymers such as polyaniline remain of widespread interest, providing an opportunity to address fundamental issues of importance to condensed matter physics, including, for example, the metal-insulator transition, the Peierls Instability and quantum decoherence.

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