Photoinitiator - Atmospheric Photoinitiators - Nitrogen Dioxide

Nitrogen Dioxide

Nitrogen dioxide can also be photolytically cleaved by photons of wavelength less than 400 nm producing atomic oxygen and nitric oxide.

NO2 → NO + O

Atomic oxygen is a highly reactive species, and can abstract a H atom from anything, including water.

O + H2O → 2 ·OH

Nitrogen dioxide can be regenerated through a reaction between certain peroxy-containing radicals and NO.

ROO· + NO → NO2 + RO·

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