Presidents of PDVSA
- Rafael Ramírez (2004 - current) Minister of Energy and Oil (2005), M.Sc. Energy policy - UCV, B.Sc Mechanical Engineering - ULA.
- Alí Rodríguez Araque (2002–2004) Minister of Energy (1999), Secretary General OPEC (2001), Lic. Economics - UCV.
- Gastón Parra Luzardo (2002) Academic Vice-Rector - LUZ (1980–1984), Dean of the School of Social Sciences - LUZ (1972–1975). Lic. Economics - LUZ.
- Guaicaipuro Lameda (October 2000 - February 2002) Brigadier General of the Venezuelan Army.
- Héctor Ciavaldini (2000 - October 2000).
- Roberto Mandini (1999).
- Luis Giusti (1994–1998) M.Sc. Petroleum Engineering - TU, B.Sc Petroleum Engineering - LUZ
- Gustavo Roosen (1992–1994) Minister of Education (1989), M.A. Comparative Law - New York University (NYU), B.A. Law - UCAB.
- Andres Sosa Pietri (1990–1992).
- Humberto Calderón Berti (1983–1984) Minister of Energy (1979–1982).
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