Structure and Properties
Oximes exist as two geometric stereoisomers: a syn isomer and an anti isomer. Aldoximes, except for aromatic aldoximes which exist only as anti isomers, and ketoximes can be separated almost completely and obtained as a syn isomer and an anti isomer.
Oximes have three characteristic bands in the infrared spectrum, at wavenumbers 3600 (O-H), 1665 (C=N) and 945 (N-O).
In aqueous solution, aliphatic oximes are 102- to 103-fold more resistant to hydrolysis than analogous hydrazones.
Read more about this topic: Oxime
Famous quotes containing the words structure and, structure and/or properties:
“With sixty staring me in the face, I have developed inflammation of the sentence structure and definite hardening of the paragraphs.”
—James Thurber (18941961)
“In the extent and proper structure of the Union, therefore, we behold a republican remedy for the diseases most incident to republican government.”
—James Madison (17511836)
“The reason why men enter into society, is the preservation of their property; and the end why they choose and authorize a legislative, is, that there may be laws made, and rules set, as guards and fences to the properties of all the members of the society: to limit the power, and moderate the dominion, of every part and member of the society.”
—John Locke (16321704)