Nuclear Binding Energy - Binding Energy For Atoms

Binding Energy For Atoms

The binding energy of an atom (including its electrons) is not the same as the binding energy of the atom's nucleus. The measured mass deficits of isotopes are always listed as mass deficits of the neutral atoms of that isotope, and mostly in MeV. As a consequence, the listed mass deficits are not a measure for the stability or binding energy of isolated nuclei, but for the whole atoms. This has very practical reasons, because it is very hard to totally ionize heavy elements, i.e. strip them of all of their electrons.

This practice is useful for other reasons, too: Stripping all the electrons from a heavy unstable nucleus (thus producing a bare nucleus) changes the lifetime of the nucleus, indicating that the nucleus cannot be treated independently (Experiments at the heavy ion accelerator GSI). This is also evident from phenomena like electron capture. Theoretically, in orbital models of heavy atoms, the electron orbits partially inside the nucleus (it doesn't orbit in a strict sense, but has a non-vanishing probability of being located inside the nucleus).

A nuclear decay happens to the nucleus, meaning that properties ascribed to the nucleus change in the event. In the field of physics the concept of "mass deficit" as a measure for "binding energy" means "mass deficit of the neutral atom" (not just the nucleus) and is a measure for stability of the whole atom.