Route Description
NY 99 began at an intersection with NY 30 west of the hamlet of Duane Center in the town of Duane. The route headed eastward as the Port Kent–Hopkinton Turnpike, passing through the small community of Duane Center before entering an isolated, wooded area of Franklin County and Adirondack Park. At the Franklin town line, NY 99 curved southeastward, roughly paralleling Hatch Brook as it climbed up the northeastern portion of Baldface Mountain. Past the mountain's summit, the route continued onward, winding its way southward along Hatch Brook to a small lake known as Duck Pond.
Past Duck Pond, the route turned to the southeast, passing by a series of small ponds and crossing under an old railroad grade as it ran along the base of a series of peaks known as the Loon Lake Mountains. NY 99 continued to follow the range to the northwestern edge of Loon Lake, where it veered to the northeast and ran along the northern and eastern shores of the lake to the hamlet of Loon Lake at its southeastern tip. NY 99 passed generally northwest–southeast through the small lakeside community before reentering another sparsely developed area of the town of Franklin. The highway progressed southeastward, crossing over the northern branch of the Saranac River and passing through the largely undeveloped community of Merrillsville before ending at an intersection with NY 3.
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