Multiferroics - History

History

The term multiferroic was first used by H. Schmid in 1994. His definition referred to multiferroics as single phase materials which simultaneously possess two or more primary ferroic properties. Today the term multiferroic has been expanded to include materials which exhibit any type of long range magnetic ordering, spontaneous electric polarization, and/or ferroelasticity. Working under this expanded definition the history of magnetoelectric multiferroics can be traced back to the 1960s. In the most general sense the field of multiferroics was born from studies of magnetoelectric systems. After an initial burst of interest, research remained static until early 2000 (see figure). In 2003 the discovery of large ferroelectric polarization in epitaxially grown thin films of BiFeO3 and the discovery of strong magnetic and electric coupling in orthorhombic TbMnO3 and TbMn2O5 re-stimulated activity in the field of multiferroics.

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