Migratory Insertion - Insertion of Alkenes Into Metal-carbon Bonds

Insertion of Alkenes Into Metal-carbon Bonds

The insertion of alkenes into both metal-carbon is important. The insertion of ethylene and propylene into titanium alkyls is the cornerstone of Ziegler-Natta catalysis, the main source of polyethylene and polypropylene. The majority of this technology involves heterogeneous catalysts, but it is widely assumed that the principles and observations on homogeneous systems are applicable to the solid-state versions. Related technologies include the Shell Higher Olefin Process which produces detergent precursors.

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