Low Self-discharge Ni MH Battery - Charging - Safety

Safety

A good safety feature of a custom-built charger is to use a resettable fuse in series with the cell, particularly of the bimetallic strip type. This fuse will open if either the current or the temperature goes too high.

Modern NiMH cells contain catalysts to immediately deal with gases developed as a result of over-charging without being harmed (2 H2 + O2 ---catalyst → 2 H2O). However, this only works with overcharging currents of up to 0.1C (nominal capacity divided by 10 hours). As a result of this reaction, the batteries will heat up considerably, marking the end of the charging process. Some quick chargers have a fan to keep the batteries cool.

A method for very rapid charging called in-cell charge control involves an internal pressure switch in the cell, which disconnects the charging current in the event of overpressure.

There is an inherent risk with NiMH chemistry that overcharging will cause a buildup of hydrogen, causing the cell to rupture. Therefore, cells have a vent. Hydrogen will be emitted from the vent in the event of serious overcharging.

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