Lonsdaleite - Properties

Properties

Lonsdaleite has a hexagonal unit cell, related to the diamond unit cell in the same way that the hexagonal and cubic close packed crystal systems are related. The diamond structure can be considered to be made up of interlocking rings of six carbon atoms, in the chair conformation. In lonsdaleite, some of the rings are in the boat conformation instead. In diamond, all the carbon-to-carbon bonds, both within a layer of rings and between them, are in the staggered conformation, thus causing all four cubic-diagonal directions to be equivalent; while in lonsdaleite the bonds between layers are in the eclipsed conformation, which defines the axis of hexagonal symmetry.

Lonsdaleite is simulated to be 58% harder than diamond on the <100> face and to resist indentation pressures of 152 GPa, whereas diamond would break at 97 GPa. This is still below IIa diamond's <111> tip hardness of 162 GPa.

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