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- Anton Saefkow, German resistance (1964)
- Gustl Sandner, German resistance (1960)
- Ferdinand von Schill (1953)
- Friedrich von Schiller (1955, 1959)
- Paul Schneider (1957)
- Ernst Schneller, German resistance (1960)
- Franz Schubert, composer (1953)
- Harro Schulze-Boysen, German Resistance (1983)
- Robert Schumann, composer (1956)
- Werner Seelenbinder, athlete, German Resistance fighter, (1964)
- John Sieg, German Resistance (1983)
- Joseph Stalin (1951, 1954)
- Heinrich Friedrich Karl Reichsfreiherr vom und zum Stein (1953)
Read more about this topic: List Of People On Stamps Of The German Democratic Republic