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- Nicholas Van Dyke (1738–1789), Continental Congressman and President of Delaware
- Nicholas Van Dyke (1770–1826), U.S. Representative and U.S. Senator from Delaware
- James C. Van Sice, Rear Admiral in the U.S. Coast Guard; born in Wilmington
- Francis D. Vavala, (1947-), Major General, National Guard Adjutant General
- Tom Verlaine, musician
- John M. Vining (1758–1802), U.S. Representative and U.S. Senator from Delaware
Read more about this topic: List Of People From Delaware