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- Pierre-François de Saint-Martial,
- Claude-Anne de Saint-Simon, (Marquess), (1743–1819), deputy of the nobility of the bailiwick of Angoulême.
- Christophe Saliceti, (1757–1809), deputy of the Third Estate of the Island of Corsica.
- Étienne François Sallé de Chou (1754–1832), deputy of the Berry.
- Louis-Joseph Schmits (1758–1819), deputy of the Third Estate of the bailiwick of Sarreguemines
- Emmanuel-Joseph Sieyès (1748–1836).
Read more about this topic: List Of Members Of The National Constituent Assembly Of 1789