Edinburgh
- 1 Giant Leap featuring Will Young, Maxi Jazz, Neneh Cherry, Geoffrey Oryema, and Mahotella Queens
- Annie Lennox (also appeared in London)
- Beverley Knight
- Bob Geldof (also appeared in London) and Campino (from Die Toten Hosen who also appeared in Berlin)
- Bono (presenter, also appeared with his band U2 at London)
- Chris Evans
- Claudia Schiffer (presenter, also appeared in Berlin)
- Coumi Nidu (Action Against Poverty)
- Davina McCall (presenter)
- Eddie Izzard (presenter, also accompanied Midge Ure)
- Embrace
- Feeder
- George Clooney (presenter)
- Herbert Grönemeyer (also appeared in Berlin)
- James Brown (featuring Will Young)
- Jamie Cullum
- Katherine Jenkins (also appeared in Berlin)
- Lenny Henry (presenter, also appeared in London)
- McFly (also appeared in Tokyo)
- Midge Ure
- Natasha Bedingfield
- Nelson Mandela (prerecorded speech, also a host in Johannesburg)
- Neneh Cherry
- Peter Kay (presenter, also appeared in London)
- Ronan Keating
- Snow Patrol (also appeared in London)
- Sugababes
- Susan Sarandon (presenter)
- Texas
- The Corrs
- The Proclaimers
- The Thrills
- Travis (also appeared in London)
- Wangari Maathai (presenter)
- Wet Wet Wet
Read more about this topic: List Of Live 8 Artists