Cornwall
- Akim El Sikameya
- Angelina Jolie (presenter & Goodwill Ambassador)
- Angelique Kidjo
- Ayub Ogada
- Ayub Ogada & Uno
- Chartwell Dutiro
- Coco Mbassi
- Daara J
- Dido (also appeared in London and Paris)
- Emmanuel Jal
- Frititi
- Geoffrey Oryema
- Kanda Bongo Man
- Mariza
- Maryam Mursal
- Modou Diouf & O Fogum
- Peter Gabriel & Johnny Kalsi (Hosts)
- Shikisha
- Siyaya
- Thomas Mapfumo & the Blacks Unlimited
- Tinariwen
- Youssou N'Dour and Super Etoile de Dakar (also appeared in London, and Paris)
Read more about this topic: List Of Live 8 Artists