Romania
- Gavril Balint – Burgos CF – 1990–93
- Constantin Barbu – CD Numancia – 1999–01
- Miodrag Belodedici – Valencia CF, Real Valladolid – 1992–95
- Cosmin Contra – Alavés, Atlético Madrid, Getafe CF – 1999–01, 2002–04, 2005–10
- Gică Craioveanu – Real Sociedad, Villarreal CF, Getafe CF – 1995–99, 2000–02, 2004–06
- Ilie Dumitrescu – Sevilla FC – 1994–95
- Iulian Filipescu – Real Betis – 1998–00, 2001–03
- Constantin Gâlcă – RCD Espanyol, Villarreal CF – 1997–03
- Gheorghe Hagi – Real Madrid, FC Barcelona – 1990–92, 1994–96
- Adrian Ilie – Valencia CF, Alavés – 1997–03
- Marius Iordache – Villarreal CF – 1998–99
- Marius Lăcătuş – Real Oviedo – 1991–93
- Silviu Lung – CD Logroñés – 1990–91
- Bogdan Mara – Alavés – 2001–03
- Lucian Marinescu – UD Salamanca – 1998–99
- Dorin Mateuţ – Real Zaragoza – 1990–93
- Cătălin Munteanu – UD Salamanca, RCD Espanyol, Albacete – 1998–99, 2001–02, 2003–04
- Nicolae Simatoc – FC Barcelona, Real Oviedo – 1950–53
- Gabriel Popescu – UD Salamanca, Valencia CF, CD Numancia – 1997–00
- Gheorghe Popescu – FC Barcelona – 1995–97
- Daniel Prodan – Atlético Madrid – 1996–98
- Cristian Pulhac – Hércules CF – 2010–11
- Claudiu Răducanu – RCD Espanyol – 2003–04
- Florin Răducioiu – RCD Espanyol – 1994–97
- Laurenţiu Roşu – CD Numancia, Recreativo de Huelva – 2000–01, 2006–08
- Marcel Sabou – CD Tenerife, Sporting de Gijón – 1990–91, 1993–96
- Cristian Săpunaru – Real Zaragoza – 2012–13
- László Sepsi – Racing – 2008–10
- Dennis Şerban – Valencia CF – 1998–00, 2001–02
- Bogdan Stelea – RCD Mallorca, UD Salamanca – 1991–92, 1997–99
- Ovidiu Stîngă – UD Salamanca – 1995–96
- Gabriel Tamaş – Celta de Vigo – 2006–07
- Gabriel Torje – Granada CF – 2012–13
Read more about this topic: List Of Foreign La Liga Players