Nigeria
- Mutiu Adepoju – Racing, Real Sociedad – 1993-00
- Wilfred Agbonavbare – Rayo Vallecano – 1992-94, 1995–96
- Festus Agu – SD Compostela – 1995-96
- Emmanuel Amuneke – FC Barcelona – 1996-97
- Finidi George – Real Betis, RCD Mallorca – 1996-01, 2003–04
- Victor Ikpeba – Real Betis – 2001-02
- Christopher Kanu – Alavés – 2001-02
- Abass Lawal – Albacete – 2003-05
- Bartholomew Ogbeche – Real Valladolid – 2007-09
- Christopher Ohen – SD Compostela – 1994-98
- Okunowo – FC Barcelona – 1998-99
- Peter Rufai – Hércules CF, Deportivo de La Coruña – 1996-99
- Ikechukwu Uche – Recreativo de Huelva, Getafe CF, Real Zaragoza – 2006-10
- Kalu Uche – UD Almería – 2007-10
- Nduka Ugbade – CD Castellón – 1989-91
- Rashidi Yekini – Sporting de Gijón – 1995-97
Read more about this topic: List Of Foreign La Liga Players