Chile
- Jorge Aravena – Real Valladolid – 1985-86
- Osvaldo "Arica" Hurtado – Cádiz CF – 1985-86
- Claudio Bravo – Real Sociedad – 2006-07, 2010–11
- Fernando Carvallo – Cádiz CF – 1977-78
- Carlos Caszely – RCD Espanyol – 1975-78
- Jorge Contreras – UD Las Palmas – 1985-88
- Pablo Contreras – CA Osasuna, Celta de Vigo – 2001-02, 2003–04, 2005–07
- Guillermo Díaz – Real Zaragoza – 1952-53
- Mati Fernández – Villarreal CF – 2006-09
- Gabriel Galleguillos – UD Salamanca – 1975-77
- Mark González – Albacete, Real Sociedad, Real Betis – 2004-06, 2007–09
- Gary Medel – Sevilla FC2011
- Raúl Muñoz – CD Numancia – 1999-00
- Rafael Olarra – CA Osasuna – 2001-02
- Fabián Orellana– Xerez – 2009-10
- Mauricio Pinilla – Celta de Vigo, Racing – 2003-04, 2005–06
- Waldo Ponce- Racing de Santander- 2010-11
- Andrés Prieto – RCD Espanyol – 1953-55
- Jaime Ramírez – RCD Espanyol, Granada CF – 1952-54, 1957–60, 1963–64
- Miguel Ramírez – Real Sociedad – 1995-96
- Francisco Rojas – CD Tenerife – 1996-97
- Alexis Sánchez - FC Barcelona - 2011-
- Fernando Santís – UD Las Palmas – 1985-86
- César Santis – RCD Espanyol – 1999-00
- José Luis Sierra – Real Valladolid – 1989-90
- Humberto Suazo - Real Zaragoza - 2009-10
- Marcelo Vega – CD Logroñés – 1992-93
- Oscar Wirth – Real Valladolid – 1986-88
- Patricio Yáñez – Real Valladolid, Real Zaragoza, Real Betis – 1982-89
- Iván Zamorano – Sevilla FC, Real Madrid – 1990-96
Read more about this topic: List Of Foreign La Liga Players