Spanish Empire
- Viceroyalty of New Granada - Antonio José Amar y Borbón Arguedas, Viceroy of New Granada (1803–1810)
- Viceroyalty of New Spain - José Joaquín Vicente de Iturrigaray y Aróstegui, Viceroy of New Spain (1803–1808)
- Captaincy General of Cuba - Salvador de Muro y Salazar, marqués de Someruelos, Governor of Cuba (1799–1812)
- Spanish East Indies - Mariano Fernández de Folgueras, Governor-General of the Philippines (1806–1810)
- Commandancy General of the Provincias Internas - Nemesio Salcedo y Salcedo (1802–1813)
- Viceroyalty of Peru - José Fernando Abascal y Sousa, marqués de la Concordia, Viceroy of Peru (1806–1816)
- Captaincy General of Chile - Luis Muñoz de Guzmán, Governor and Captain-General of Chile (1802–1808)
- Viceroyalty of the Río de la Plata -
- Rafael de Sobremonte, Viceroy of the Río de la Plata (1804–1807)
- Santiago de Liniers, Viceroy of the Río de la Plata (1807–1809)
Read more about this topic: List Of Colonial Governors In 1807
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