Spanish Empire
- Viceroyalty of New Granada - Antonio José Amar y Borbón, Viceroy of New Granada (1803–1810)
- Viceroyalty of New Spain - José de Iturrigaray y Aréstegui, Viceroy of New Spain (1803–1808)
- Captaincy General of Cuba - Salvador de Muro y Salazar, Governor of Cuba (1799–1812)
- Spanish East Indies -
- Rafael María de Aguilar y Ponce de León, Governor-General of the Philippines (1793–1806)
- Mariano Fernández de Folgueras, Governor-General of the Philippines (1806–1810)
- Commandancy General of the Provincias Internas - Nemesio Salcedo y Salcedo (1802–1813)
- Viceroyalty of Peru -
- Gabriel de Avilés y del Fierro, Viceroy of Perú (1801–1806)
- José Fernando de Abascal y Sousa, Viceroy of Perú (1806–1816)
- Captaincy General of Chile - Luis Muñoz de Guzmán, Royal Governor of Chile (1802–1808)
- Viceroyalty of the Río de la Plata - Rafael de Sobremonte, Viceroy of the Río de la Plata (1804–1807)
Read more about this topic: List Of Colonial Governors In 1806
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