Liouville's Theorem (Hamiltonian) - Remarks

Remarks

  • The Liouville equation is valid for both equilibrium and nonequilibrium systems. It is a fundamental equation of nonequilibrium statistical mechanics. Its application to dilute gases is called the Boltzmann equation.
  • The Liouville equation is integral to the proof of the fluctuation theorem from which the second law of thermodynamics can be derived. It is also the key component of the derivation of Green-Kubo relations for linear transport coefficients such as shear viscosity, thermal conductivity or electrical conductivity.
  • Virtually any textbook on Hamiltonian mechanics, advanced statistical mechanics, or symplectic geometry will derive the Liouville theorem.

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