Electrochemistry
In electrochemistry, the phrase in situ refers to performing electrochemical experiments under operating conditions of the electrochemical cell, i.e., under potential control. This is opposed to doing ex situ experiments that are performed under the absence of potential control. Potential control preserves the electrochemical environment essential to maintain the double layer structure intact and the electron transfer reactions occurring at that particular potential in the electrode/electrolyte interphasial region.
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