Hydrolysis Constant

A hydrolysis constant is an equilibrium constant for a hydrolysis reaction.

For example, if a metal salt such as AlCl3 dissolves in an aqueous solution, the metal cation behaves as a Lewis acid and hydrolyzes the water molecules in the solvent.

Al3+ + 2H2O → AlOH2+ + H3O+

The hydrolysis constant for this reaction is as shown:

Khydrolysis = * /

In a more generalized form, the hydrolysis constant can be described as:

Ka = * /

where A- represents any base, and HA represents any acid.

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