Han Purple and Han Blue - Preservation

Preservation

Due to the instability of Han purple, it shows significant signs of weathering on archaeologically excavated artifacts. The copper(I) oxide formed in the decomposition of Han purple (see section on color) remains stable, but Han purple continues to deteriorate and so its purple color increases with time.

Han purple fades in acid, so colorless particles found in pigments containing Han blue and Han purple may be particles which were originally purple but which faded in acidic conditions in burial. In addition, Han blue has fungicidal properties and so preserves better. Han purple reacts with oxalic acid to form BaCu(C2O4)2. The light blue color of this salt may explain the light blue color of some of the Terracotta Warriors' trousers - the color resulting from the presence of oxalate-excreting lichens.

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