Group 4 Element - Occurrence

Occurrence

If the abundance of elements in Earth's crust is compared for titanium, zirconium and hafnium, the abundance decreases with increase of atomic mass. Titanium is the seventh most abundant metal in Earth's crust and has an abundance of 6320 ppm, while zirconium has an abundance of 162 ppm and hafnium has only an abundance of 3 ppm.

All three stable elements occur in heavy mineral sands ore deposits, which are placer deposits formed, most usually in beach environments, by concentration due to the specific gravity of the mineral grains of erosion material from mafic and ultramafic rock. The titanium minerals are mostly anatase and rutile, and zirconium occurs in the mineral zircon. Because of the chemical similarity, up to 5% of the zirconium in zircon is replaced by hafnium. The largest producers of the group 4 elements are Australia, South Africa and Canada.

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