1960s
- Grammy Awards of 1969
- Carlo Felice Cillario (conductor), Montserrat Caballé & the RCA Italiana Opera Orchestra & Chorus for Rossini: Rarities
- Grammy Awards of 1968
- Francesco Molinari-Pradelli (conductor), Leontyne Price, & the RCA Italiana Opera Orchestra for Prima Donna, Volume 2
- Grammy Awards of 1967
- Francesco Molinari-Pradelli (conductor), Leontyne Price & the RCA Italiana Opera Orchestra for Prima Donna (Works of Barber, Purcell, etc.)
- Grammy Awards of 1966
- Erich Leinsdorf (conductor), Leontyne Price & the Boston Symphony Orchestra for Strauss: Salome (Dance of the Seven Veils, Interlude, Final Scene)/The Egyptian Helen (Awakening Scene)
- Grammy Awards of 1965
- Fritz Reiner (conductor), Leontyne Price & the Chicago Symphony Orchestra for Berlioz: Nuits d'Ete (Song Cycle)/Falla: El Amor Brujo
- Grammy Awards of 1964
- Skitch Henderson (conductor), Leontyne Price & the RCA Orchestra for Great Scenes From Gershwin's Porgy and Bess
- Grammy Awards of 1963
- Leonard Bernstein (conductor), Eileen Farrell & the New York Philharmonic for Götterdämmerung - Brünnhilde's Immolation Scene/Wesendonck Songs
- Grammy Awards of 1962
- Francesco Molinari-Pradelli (conductor), Joan Sutherland & the Royal Opera House Orchestra for The Art of the Prima Donna
- Grammy Awards of 1961
- Leontyne Price for A Program of Song - Leontyne Price Recital
- Grammy Awards of 1960
- Jussi Björling for Bjoerling in Opera
Read more about this topic: Grammy Award For Best Classical Vocal Solo