Function
Glycogen is a branching polymer of large numbers of glucose units linked together. The structure is based on chains of glucose units with α(1→4) glycosidic bonds between carbon atoms 1 and 4 of each pair of units. These linkages are catalyzed by the enzyme glycogen synthase.
Every 10 to 14 glucose units, a side branch with an additional chain of glucose units occurs. The side chain attaches at carbon atom 6 of a glucose unit, and the linkage is termed an α(1→6) glycosidic bond. This connection is catalyzed by a branching enzyme. A branching enzyme attaches a string of seven glucose units to the sixth carbon of a glucose unit, usually in an interior location of the glycogen molecule.
Read more about this topic: Glycogen Branching Enzyme
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