Transformation Toughening
Composites exhibiting the highest level of fracture toughness are typically made of a pure alumina or some silica-alumina (SiO2 /Al2O3) matrix with tiny inclusions of zirconia (ZrO2) dispersed as uniformly as possible within the solid matrix. (*Note: a wet chemical approach is typically necessary in order to establish the compositional uniformity of the ceramic body before firing).
The process of "transformation toughening" is based on the assumption that zirconia undergoes several martensitic (displacive, diffusionless) phase transformations (cubic → tetragonal → monoclinic) between room temperature and practical sintering (or firing) temperatures. Thus, due to the volume restrictions induced by the solid matrix, metastable crystalline structures can become frozen in which impart an internal strain field surrounding each zirconia inclusion upon cooling. This enables a zirconia particle (or inclusion) to absorb the energy of an approaching crack tip front in its nearby vicinity.
Thus, the application of large shear stresses during fracture nucleates the transformation of a zirconia inclusion from the metastable phase. The subsequent volume expansion from the inclusion (via an increase in the height of the unit cell) introduces compressive stresses which therefore strengthen the matrix near the approaching crack tip front. Zirconia "whiskers" may be used expressly for this purpose.
Appropriately referred to by its first discoverers as "ceramic steel", the stress intensity factor values for window glass (silica), transformation toughened alumina, and a typical iron/carbon steel range from 1 to 20 to 50 respectively.
Read more about this topic: Fracture Toughness