Emulsion - Emulsifiers

Emulsifiers

An emulsifier (also known as an "emulgent") is a substance that stabilizes an emulsion by increasing its kinetic stability. One class of emulsifiers is known as "surface active substances", or surfactants.

Examples of food emulsifiers are:

  • Egg yolk - in which the main emulsifying agent is lecithin. In fact, lecithos is the Greek word for egg yolk.
  • Mustard - where a variety of chemicals in the mucilage surrounding the seed hull act as emulsifiers
  • Proteins
  • Low molecular weight emulsifiers
  • Soy lecithin is another emulsifier and thickener
  • Pickering stabilization - uses particles under certain circumstances
  • sodium stearoyl lactylate
  • DATEM (Diacetyl Tartaric (Acid) Ester of Monoglyceride) - an emulsifier primarily used in baking

Detergents are another class of surfactants, and will physically interact with both oil and water, thus stabilizing the interface between the oil and water droplets in suspension. This principle is exploited in soap, to remove grease for the purpose of cleaning. Many different emulsifiers are used in pharmacy to prepare emulsions such as creams and lotions. Common examples include emulsifying wax, cetearyl alcohol, polysorbate 20, and ceteareth 20. Sometimes the inner phase itself can act as an emulsifier, and the result is a nanoemulsion, where the inner state disperses into "nano-size" droplets within the outer phase. A well-known example of this phenomenon, the "Ouzo effect", happens when water is poured into a strong alcoholic anise-based beverage, such as ouzo, pastis, arak, or raki. The anisolic compounds, which are soluble in ethanol, then form nano-size droplets and emulsify within the water. The resulting color of the drink is opaque and milky white.

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