Electronegativity - Group Electronegativity

In organic chemistry, electronegativity is associated more with different functional groups than with individual atoms. The terms group electronegativity and substituent electronegativity are used synonymously. However, it is common to distinguish between the inductive effect and the resonance effect, which might be described as σ- and π-electronegativities respectively. There are a number of linear free-energy relationships which have been used to quantify these effects, of which the Hammett equation is the best known. Kabachnik parameters are group electronegativities for use in organophosphorus chemistry.

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Famous quotes containing the word group:

    Stripped of ethical rationalizations and philosophical pretensions, a crime is anything that a group in power chooses to prohibit.
    Freda Adler (b. 1934)