Electric Charge - Overview

Overview

Charge is the fundamental property of forms of matter that exhibit electrostatic attraction or repulsion in the presence of other matter. Electric charge is a characteristic property of many subatomic particles. The charges of free-standing particles are integer multiples of the elementary charge e; we say that electric charge is quantized. Michael Faraday, in his electrolysis experiments, was the first to note the discrete nature of electric charge. Robert Millikan's oil-drop experiment demonstrated this fact directly, and measured the elementary charge.

By convention, the charge of an electron is −1, while that of a proton is +1. Charged particles whose charges have the same sign repel one another, and particles whose charges have different signs attract. Coulomb's law quantifies the electrostatic force between two particles by asserting that the force is proportional to the product of their charges, and inversely proportional to the square of the distance between them.

The charge of an antiparticle equals that of the corresponding particle, but with opposite sign. Quarks have fractional charges of either −1⁄₃ or +2⁄₃, but free-standing quarks have never been observed (the theoretical reason for this fact is asymptotic freedom).

The electric charge of a macroscopic object is the sum of the electric charges of the particles that make it up. This charge is often small, because matter is made of atoms, and atoms typically have equal numbers of protons and electrons, in which case their charges cancel out, yielding a net charge of zero, thus making the atom neutral.

An ion is an atom (or group of atoms) that has lost one or more electrons, giving it a net positive charge (cation), or that has gained one or more electrons, giving it a net negative charge (anion). Monatomic ions are formed from single atoms, while polyatomic ions are formed from two or more atoms that have been bonded together, in each case yielding an ion with a positive or negative net charge.

Electric field induced by a positive electric charge (left) and a field induced by a negative electric charge (right).

During the formation of macroscopic objects, usually the constituent atoms and ions will combine in such a manner that they form structures composed of neutral ionic compounds electrically bound to neutral atoms. Thus macroscopic objects tend toward being neutral overall, but macroscopic objects are rarely perfectly net neutral.

There are times when macroscopic objects contain ions distributed throughout the material, rigidly bound in place, giving an overall net positive or negative charge to the object. Also, macroscopic objects made of conductive elements, can more or less easily (depending on the element) take on or give off electrons, and then maintain a net negative or positive charge indefinitely. When the net electric charge of an object is non-zero and motionless, the phenomenon is known as static electricity. This can easily be produced by rubbing two dissimilar materials together, such as rubbing amber with fur or glass with silk. In this way non-conductive materials can be charged to a significant degree, either positively or negatively. Charge taken from one material is moved to the other material, leaving an opposite charge of the same magnitude behind. The law of conservation of charge always applies, giving the object from which a negative charge has been taken a positive charge of the same magnitude, and vice-versa.

Even when an object's net charge is zero, charge can be distributed non-uniformly in the object (e.g., due to an external electromagnetic field, or bound polar molecules). In such cases the object is said to be polarized. The charge due to polarization is known as bound charge, while charge on an object produced by electrons gained or lost from outside the object is called free charge. The motion of electrons in conductive metals in a specific direction is known as electric current.