History
Modern chemical refrigeration techniques developed after the proposal of the Carnot cycle in 1824. Jacob Perkins invented an ice-making machine that used ether in 1843, and Edmond Carré built a refrigerator that used water and sulfuric acid in 1850. In Japan, Fusanosuke Kuhara, founder of Hitachi, Ltd., made an air conditioner for his own home use using compressed CO2 as a refrigerant.
In 1930 Thomas Midgley, Jr. discovered dichlorodifluoromethane, a chlorinated fluorocarbon (CFC) known as freon. CFCs rapidly replaced traditional refrigerant substances, including CO2 (which proved hard to compress for domestic use), for use in heat pumps and refrigerators. But from the 1980s CFCs began to lose favor as refrigerant when their damaging effects on the ozone layer were discovered. Two alternative types of refrigerant, hydrofluorocarbons (HFCs) and hydrochlorofluorocarbons (HCFCs), also lost favour when they were identified as greenhouse gases (additionally, HCFCs were found to be more damaging to the ozone layer than originally thought). The Vienna Convention for the Protection of the Ozone Layer, the Montreal Protocol and the Kyoto Protocol call for the complete abandonment of such refrigerants by 2030.
In 1989, amid international concern about the effects of chlorofluorocarbons and hydrochlorofluorocarbons on the ozone layer, scientist Gustav Lorentzen and SINTEF patented a method for using CO2 as a refrigerant in heating and cooling. Further research into CO2 refrigeration was then conducted at Shecco (Sustainable Heating and Cooling with CO2) in Brussels, Belgium, leading to increasing use of CO2 refrigerant technology in Europe.
In 1993 the Japanese company Denso, in collaboration with Gustav Lorentzen, developed an automobile air conditioner using CO2 as a refrigerant. They demonstrated the invention at the June 1998 International Institute of Refrigeration/Gustav Lorentzen Conference. After the conference, CRIEPI (Central Research Institute of Electric Power Industry) and TEPCO (The Tokyo Electric Power Company) approached Denso about developing a prototype air conditioner using natural refrigerant materials instead of freon. Together they produced 30 prototype EcoCute units for a year-long experimental installation at locations throughout Japan, from the cold climate of Hokkaidō to hotter Okinawa. After this successful feasibility study, Denso obtained a patent to compress CO2 refrigerant for use in a heat pump from SINTEF in September 2000.
The first commercial domestic EcoCute was marketed in Japan by Corona Corporation in May 2001, and several manufacturers sold 1.5 million units there by October, 2008.
FEPC reported 2 million EcoCute units had been delivered by end of October 2009, with the equivalent CO2 absorption of 9400 km² of forest.
Read more about this topic: Eco Cute
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—Walter Bagehot (1826–1877)
“There is a history in all men’s lives,
Figuring the natures of the times deceased,
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With a near aim, of the main chance of things
As yet not come to life.”
—William Shakespeare (1564–1616)