People
- Adolfo Domínguez (born 1950), Spanish fashion designer
- Alberto González Domínguez Argentine mathematician
- Alejandro Damián Domínguez (born 1981), Argentine football player
- Alejandro Domínguez Coello (died 2005), former chief of police in Nuevo Laredo, Mexico who was assassinated in 2005
- Albino Núñez Domínguez (1901 –1974), Galician writer and poet.
- Alfonso Martínez Domínguez (1922–2002), Mexican politician, mayor of Mexico City 1970–1971
- Álvaro Domínguez Soto (b. 1989), Spanish soccer player
- Clemente Domínguez y Gómez (1946–2005), Spanish churchman, pope of the Palmarian Catholic Church (antipope)
- Cinthya Domínguez (born 1982), Mexican weightlifter
- Diego Domínguez (born 1966), Argentine rugby player
- Federico Hernán Domínguez (born 1976), Argentine football player
- Francisco Atanasio Domínguez (18th century), Franciscan missionary and explorer in North America
- Francisco Serrano y Domínguez, Duke de la Torre (1810–1885), Spanish marshal and statesman
- Josefa "La Corregidora" Ortiz de Domínguez (1768–1829), Mexican conspirator, spouse of corregidor Miguel Domínguez
- Juanjo Domínguez (contemporary), Argentine classical guitarist
- Kristen Forrester Dominguez, fictional character in the American soap opera The Bold and the Beautiful
- Liliana Domínguez (contemporary), Mexican supermodel
- Lourdes Domínguez Lino (born 1981), Spanish tennis player
- Mario Domínguez (born 1975), Mexican Champ Car racing driver
- Marta Domínguez (born 1975), Spanish track athlete in the 3000-meter and 5000-meter events
- Matt Dominguez (born 1978), American football player in the Canadian Football League
- Miguel Domínguez (1756–1830), Mexican official and corregidor of Querétaro
- Michael L. Dominguez (contemporary), U.S. Department of Defense official
- Nuria Domínguez (born 1974), Spanish rower
- Oralia Domínguez (born 1925), Mexican mezzo-soprano
- Óscar Domínguez (1906–1957), Spanish surrealist painter
- Raúl Domínguez (born 1972), Cuban track cyclist
- Ricardo Dominguez, American professor and electronic activist
- Richard Dominguez (born 1960), American comic book artist and illustrator
- Ron Dominguez (contemporary), former vice-president of Walt Disney Attractions
- Sally Dominguez (born 1969), Australian inventor
- Wade Domínguez (1966–1998) American actor, model and singer
- Juan Dominguez y Valdez, Texan military
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