Water Exchange
The exchange between bulk and coordinated water is of fundamental interest as a measure of the intrinsic kinetic lability of metal ions. This rate is relevant to toxicity, catalysis, magnetic resonance imaging, and other effects. For octahedral mono- and dicationic aquo complexes, these exchange processes occur via an interchange pathway that has more or less dissociative character. Rates vary by a factor of 1018, 3+ being the slowest and + being one of the fastest for octahedral complexes. Charge has a significant influence on these rates but non-electrostatic effects are also important.
Read more about this topic: Dissociative Substitution
Famous quotes containing the words water and/or exchange:
“If water is too clear, it will not contain fish; people who are too cautious will never gain wisdom.”
—Chinese proverb.
“The first place he went into was the Royal Exchange .... where men of all ages and all nations were assembled, with no other view than to barter for interest. The countenances of most of the people showed they were filled with anxiety; some indeed appeared pleased, but yet it was with a mixture of fear.... [David] resolved to stay no longer in a place where riches were esteemed goodness, and deceit, low cunning, and giving up all things to the love of gain were thought wisdom.”
—Sarah Fielding (1710–1768)