Water Exchange
The exchange between bulk and coordinated water is of fundamental interest as a measure of the intrinsic kinetic lability of metal ions. This rate is relevant to toxicity, catalysis, magnetic resonance imaging, and other effects. For octahedral mono- and dicationic aquo complexes, these exchange processes occur via an interchange pathway that has more or less dissociative character. Rates vary by a factor of 1018, 3+ being the slowest and + being one of the fastest for octahedral complexes. Charge has a significant influence on these rates but non-electrostatic effects are also important.
Read more about this topic: Dissociative Substitution
Famous quotes containing the words water and/or exchange:
“So when Pilate saw that he could do nothing, but rather that a riot was beginning, he took some water and washed his hands before the crowd, saying, “I am innocent of this man’s blood; see to it yourselves.””
—Bible: New Testament, Matthew 27:24.
“I cannot say what poetry is; I know that our sufferings and our concentrated joy, our states of plunging far and dark and turning to come back to the world—so that the moment of intense turning seems still and universal—all are here, in a music like the music of our time, like the hero and like the anonymous forgotten; and there is an exchange here in which our lives are met, and created.”
—Muriel Rukeyser (1913–1980)