Water Exchange
The exchange between bulk and coordinated water is of fundamental interest as a measure of the intrinsic kinetic lability of metal ions. This rate is relevant to toxicity, catalysis, magnetic resonance imaging, and other effects. For octahedral mono- and dicationic aquo complexes, these exchange processes occur via an interchange pathway that has more or less dissociative character. Rates vary by a factor of 1018, 3+ being the slowest and + being one of the fastest for octahedral complexes. Charge has a significant influence on these rates but non-electrostatic effects are also important.
Read more about this topic: Dissociative Substitution
Famous quotes containing the words water and/or exchange:
“A little water clears us of this deed.
How easy is it then!”
—William Shakespeare (1564–1616)
“I can exchange opinion with any neighbouring mind,
I have as healthy flesh and blood as any rhymer’s had,
But O! my Heart could bear no more when the upland caught the wind;
I ran, I ran, from my love’s side because my Heart went mad.”
—William Butler Yeats (1865–1939)