Water Exchange
The exchange between bulk and coordinated water is of fundamental interest as a measure of the intrinsic kinetic lability of metal ions. This rate is relevant to toxicity, catalysis, magnetic resonance imaging, and other effects. For octahedral mono- and dicationic aquo complexes, these exchange processes occur via an interchange pathway that has more or less dissociative character. Rates vary by a factor of 1018, 3+ being the slowest and + being one of the fastest for octahedral complexes. Charge has a significant influence on these rates but non-electrostatic effects are also important.
Read more about this topic: Dissociative Substitution
Famous quotes containing the words water and/or exchange:
“This sand seemed to us the connecting link between land and water. It was a kind of water on which you could walk, and you could see the ripple-marks on its surface, produced by the winds, precisely like those at the bottom of a brook or lake. We had read that Mussulmans are permitted by the Koran to perform their ablutions in sand when they cannot get water, a necessary indulgence in Arabia, and we now understand the propriety of this provision.”
—Henry David Thoreau (1817–1862)
“To coöperate in the highest as well as the lowest sense, means to get our living together. I heard it proposed lately that two young men should travel together over the world, the one without money, earning his means as he went, before the mast and behind the plow, the other carrying a bill of exchange in his pocket. It was easy to see that they could not long be companions or coöperate, since one would not operate at all. They would part at the first interesting crisis in their adventures.”
—Henry David Thoreau (1817–1862)