Water Exchange
The exchange between bulk and coordinated water is of fundamental interest as a measure of the intrinsic kinetic lability of metal ions. This rate is relevant to toxicity, catalysis, magnetic resonance imaging, and other effects. For octahedral mono- and dicationic aquo complexes, these exchange processes occur via an interchange pathway that has more or less dissociative character. Rates vary by a factor of 1018, 3+ being the slowest and + being one of the fastest for octahedral complexes. Charge has a significant influence on these rates but non-electrostatic effects are also important.
Read more about this topic: Dissociative Substitution
Famous quotes containing the words water and/or exchange:
“I’d take off all my clothes
& cross the damp cold lawn & down the bluff
into the terrible water & walk forever
under it out toward the island.”
—John Berryman (1914–1972)
“Development, it turns out, occurs through this process of progressively more complex exchange between a child and somebody else—especially somebody who’s crazy about that child.”
—Urie Bronfenbrenner (b. 1917)