Diffraction - Particle Diffraction

Particle Diffraction

See also: neutron diffraction and electron diffraction

Quantum theory tells us that every particle exhibits wave properties. In particular, massive particles can interfere and therefore diffract. Diffraction of electrons and neutrons stood as one of the powerful arguments in favor of quantum mechanics. The wavelength associated with a particle is the de Broglie wavelength

where h is Planck's constant and p is the momentum of the particle (mass × velocity for slow-moving particles).

For most macroscopic objects, this wavelength is so short that it is not meaningful to assign a wavelength to them. A sodium atom traveling at about 30,000 m/s would have a De Broglie wavelength of about 50 pico meters.

Because the wavelength for even the smallest of macroscopic objects is extremely small, diffraction of matter waves is only visible for small particles, like electrons, neutrons, atoms and small molecules. The short wavelength of these matter waves makes them ideally suited to study the atomic crystal structure of solids and large molecules like proteins.

Relatively larger molecules like buckyballs were also shown to diffract.

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