Degree of Polymerization

The degree of polymerization, or DP, is usually defined as the number of monomeric units in a macromolecule or polymer or oligomer molecule.

For a homopolymer, there is only one type of monomeric unit and the number-average degree of polymerization is given by

For most industrial purposes, degrees of polymerization in the thousands or tens of thousands are desired.

Some authors, however, define DP as the number of repeat units, where for copolymers the repeat unit may not be identical to the monomeric unit. For example, in nylon-6,6, the repeat unit contains the two monomeric units —NH(CH2)6NH— and —OC(CH2)4CO—, so that a chain of 1000 monomeric units corresponds to 500 repeat units. The degree of polymerization or chain length is then 1000 by the first (IUPAC) definition, but 500 by the second.

In polycondensation, in order to achieve a high degree of polymerization (and hence molecular weight), Xn, a high fractional monomer conversion, p, is required, as per Carothers' equation: Xn = 1/(1−p). A monomer conversion of p = 99% would be required to achieve Xn = 100.

Read more about Degree Of Polymerization:  Correlation With Physical Properties, Kinds of Degree of Polymerization

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Degree Of Polymerization - Kinds of Degree of Polymerization
... Mainly, there are two types used to measure the degree of polymerization, number average degree of polymerization and weight average degree of ... Number Average degree of polymerization is found by finding the Weighted mean of mole fraction o ... While the weight average degree of polymerization is found by finding the weighted mean of weight fraction ...

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