Properties
Almost all PEX is made from high density polyethylene (HDPE). PEX contains cross-linked bonds in the polymer structure, changing the thermoplastic to a thermoset. Cross-linking is accomplished during or after the extrusion of the tubing. The required degree of cross-linking, according to ASTM Standard F 876-93, is between 65 and 89%. A higher degree of cross-linking could result in brittleness and stress cracking of the material.
The high-temperature properties of the polymer are improved. Adequate strength to 120-150°C is maintained by reducing the tendency to flow. Chemical resistance is enhanced by resisting dissolution. Low temperature properties are improved. Impact and tensile strength, scratch resistance, and resistance to brittle fracture are enhanced.
PEX- or XLPE-insulated cables have a rated maximum conductor temperature of 90°C and an emergency rating up to 140°C, depending on the standard used. They have a conductor short-circuit rating of 250°C.
XLPE has excellent dielectric properties, making it useful for medium voltage - 10 to 50 kV AC - and high voltage cables - up to 380 kV AC-voltage, and several hundred kV DC.
Numerous modifications in the basic polymer structure can be made to maximize productivity during the manufacturing process. For medium voltage applications, reactivity can be boosted significantly. This results in higher line speeds in cases where limitations in either the curing or cooling processes within the continuous vulcanization (CV) tubes used to cross-link the insulation. PEX insulations can be modified to limit the amount of by-product gases generated during the cross-linking process. This is particularly useful for high voltage cable and extra-high voltage cable applications, where degassing requirements can significantly lengthen cable manufacturing time.
Read more about this topic: Cross-linked Polyethylene
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