Copolymer - Copolymer Equation

Copolymer Equation

An alternating copolymer has the formula: -A-B-A-B-A-B-A-B-A-B-, or -(-A-B-)n-. The molar ratios of the monomer in the polymer is close to one, which happens when the reactivity ratios r1 & r2 are close to zero, as given by the Mayo-Lewis equation also called the copolymerization equation:

where r1 = k11/k12 & r2 = k22/k21

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