Cloud Condensation Nuclei - Size, Abundance, and Composition

Size, Abundance, and Composition

A typical raindrop is about 2 mm in diameter, a typical cloud droplet is on the order of 0.02 mm, and a typical cloud condensation nucleus (aerosol) is on the order of 0.0001 mm or 0.1 micrometer or greater in diameter. The number of cloud condensation nuclei in the air can be measured and ranges between around 100 to 1000 per cubic centimetre. The total mass of CCNs injected into the atmosphere has been estimated at 2x1012 kg over a year's time. Large concentrations of particulates are also responsible for haze in areas with lower humidity. This dry haze also has an effect on climate by either absorbing or reflecting radiation (see albedo).

There are many different types of atmospheric particulates that can act as CCN. The particles may be composed of dust or clay, soot or black carbon from grassland or forest fires, sea salt from ocean wave spray, soot from factory smokestacks or internal combustion engines, sulfate from volcanic activity, phytoplankton or the oxidation of sulfur dioxide and secondary organic matter formed by the oxidation of VOCs. The ability of these different types of particles to form cloud droplets varies according to their size and also their exact composition, as the hygroscopic properties of these different constituents are very different. Sulfate and sea salt, for instance, readily absorb water whereas soot, organic carbon and mineral particles do not. This is made even more complicated by the fact that many of the chemical species may be mixed within the particles (in particular the sulfate and organic carbon). Additionally, while some particles (such as soot and minerals) do not make very good CCN, they do act as very good ice nuclei in colder parts of the atmosphere.

The number and type of CCNs can affect the lifetimes and radiative properties of clouds as well as the amount and hence have an influence on climate change ; the details of this are still not well understood but are the subject of research. There is also speculation that solar variation may affect cloud properties via CCNs, and hence affect climate.