Chloroacetic Acids

In organic chemistry, the chloroacetic acids (systematic name chloroethanoic acids) are three related chlorocarbon carboxylic acids:

  • Chloroacetic acid (chloroethanoic acid ), CH2ClCOOH
  • Dichloroacetic acid (dichloroethanoic acid), CHCl2COOH
  • Trichloroacetic acid (trichloroethanoic acid), CCl3COOH

As the number of chlorine atoms increases, the electronegativity of that end of the molecule increases, and the molecule adopts a progressively more ionic character: its density, boiling point and acidity all increase.

Acid Melting point (°C) Boiling point (°C) Density (g/cm3) pKa
Acetic acid 16.5 118.1 1.05 4.76
Chloroacetic acid 61-63 189 1.58 2.87
Dichloroacetic acid 9.5 194 1.57 1.25
Trichloroacetic acid 57 196 1.63 0.77

Read more about Chloroacetic Acids:  Production, Uses, Safety

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