Chirality (chemistry) - Inorganic Chemistry

Inorganic Chemistry

Many coordination compounds are chiral. At one time, the chirality was associated with organic chemistry, but this misconception was overthrown by the resolution of a purely inorganic compound, hexol, by Alfred Werner. A famous example is tris(bipyridine)ruthenium(II) complex in which the three bipyridine ligands adopt a chiral propeller-like arrangement.

In this case, the Ru atom is the stereogenic center. The two enantiomers of complexes such as 2+ may be designated as Λ (capital lambda, the Greek version of "L", for a left-handed twist of the propeller described by the ligands) and Δ (capital delta, Greek "D", for a right-handed twist).

It is now appreciated that chirality is pervasive in inorganic chemistry, an example from the mineral kingdom being quartz.

Read more about this topic:  Chirality (chemistry)

Famous quotes containing the words inorganic and/or chemistry:

    Man, unlike anything organic or inorganic in the universe, grows beyond his work, walks up the stairs of his concepts, emerges ahead of his accomplishments.
    John Steinbeck (1902–1968)

    The chemistry of dissatisfaction is as the chemistry of some marvelously potent tar. In it are the building stones of explosives, stimulants, poisons, opiates, perfumes and stenches.
    Eric Hoffer (1902–1983)