Chemical Element - Description

Description

The lightest of the chemical elements are hydrogen and helium, both created by Big Bang nucleosynthesis during the first 20 minutes of the universe in a ratio of around 3:1 by mass (approximately 12:1 by number of atoms). Almost all other elements found in nature, including some further hydrogen and helium created since then, were made by various natural or (at times) artificial methods of nucleosynthesis. On Earth, small amounts of new atoms are naturally produced in nucleogenic reactions, or in cosmogenic processes, such as cosmic ray spallation. New atoms are also naturally produced on Earth as radiogenic daughter isotopes of ongoing radioactive decay processes such as alpha decay, beta decay, spontaneous fission, cluster decay, and other rarer modes of decay.

Of the 98 naturally occurring elements, those with atomic numbers 1 through 40 are all considered to be stable. Elements with atomic numbers 41 through 82 are apparently stable (except technetium, element 43 and promethium, element 61, which are unstable) but theoretically unstable, and thus possibly mildly radioactive. The half-lives of elements 41 through 82 are so long however that their radioactive decay has yet to be detected by experiment. These "theoretical radionuclides" have half-lives at least 100 million times longer than the estimated age of the universe. Elements with atomic numbers 83 through 98 are unstable to the point that their radioactive decay can be detected. Some of these elements, notably thorium (atomic number 90) and uranium (atomic number 92), have one or more isotopes with half-lives long enough to survive as remnants of the explosive stellar nucleosynthesis that produced the heavy elements before the formation of our solar system. For example, at over 1.9×1019 years, over a billion times longer than the current estimated age of the universe, bismuth-209 (atomic number 83) has the longest known alpha decay half-life of any naturally occurring element. The very heaviest elements (those beyond californium, atomic number 98) undergo radioactive decay with half-lives so short that they do not occur in nature and have to be synthesized.

As of 2010, there are 118 known elements (in this context, "known" means observed well-enough, even from just a few decay products, to have been differentiated from any other element). Of these 118 elements, 98 occur naturally on Earth. Ten of these occur in extreme trace quantities: technetium, atomic number 43; promethium, number 61; astatine, number 85; francium, number 87; neptunium, number 93; plutonium, number 94; americium, number 95; curium, number 96; berkelium, number 97; and californium, number 98. These 98 elements have been detected in the universe at large, in the spectra of stars and also supernovae, where short-lived radioactive elements are newly being made. The first 98 elements have been detected directly on Earth as primordial nuclides present from the formation of the solar system, or as naturally-occurring fission or transmutation products of uranium and thorium.

The remaining 24 heavier elements, not found today either on Earth or in astronomical spectra, have been derived artificially. All of the heavy elements that are derived solely through artificial means are radioactive, with very short half-lives; if any atoms of these elements were present at the formation of Earth, they are extremely likely to have already decayed, and if present in novae, have been in quantities too small to have been noted. Technetium was the first purportedly non-naturally occurring element to be synthesized, in 1937, although trace amounts of technetium have since been found in nature (and also the element may have been discovered naturally in 1925). This pattern of artificial production and later natural discovery has been repeated with several other radioactive naturally-occurring rare elements.

Lists of the elements are available by name, by symbol, by atomic number, by density, by melting point, and by boiling point as well as ionization energies of the elements. The nuclides of stable and radioactive elements are also available as a list of nuclides, sorted by length of half-life for those that are unstable. One of the most convenient, and certainly the most traditional presentation of the elements, is in form of periodic table, which groups elements with similar chemical properties (and usually also similar electronic structures) together.

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