Relation To The Ideal Gas Law
French physicist Émile Clapeyron combined Charles's law with Boyle's law in 1834 to produce a single statement which would become known as the ideal gas law. Claypeyron's original statement was:
where t is the Celsius temperature; and p0, V0 and t0 are the pressure, volume and temperature of a sample of gas under some standard state. The figure of 267 came directly from Gay-Lussac's work: the modern figure would be 273.15. For any given sample of gas, p0V0⁄267+t0 is a constant (Clapeyron denoted this constant R, and it is closely related to the modern gas constant); if the pressure is also constant, the equation simplifies to
as required.
The modern statement of the ideal gas law is:
where n is the amount of substance of the gas sample; and R is the gas constant. The amount of substance is constant for any given gas sample so, at constant pressure, the equation rearranges to:
where nR⁄p is the constant of proportionality.
An ideal gas is defined as a gas which obeys the ideal gas law, so Charles' law is only expected to be followed exactly by ideal gases. Nevertheless, it is a good approximation to the behaviour of real gases at relatively high temperatures and relatively low pressures.
Read more about this topic: Charles's Law
Famous quotes containing the words relation to the, relation to, relation, ideal, gas and/or law:
“Only in a house where one has learnt to be lonely does one have this solicitude for things. One’s relation to them, the daily seeing or touching, begins to become love, and to lay one open to pain.”
—Elizabeth Bowen (1899–1973)
“To be a good enough parent one must be able to feel secure in one’s parenthood, and one’s relation to one’s child...The security of the parent about being a parent will eventually become the source of the child’s feeling secure about himself.”
—Bruno Bettelheim (20th century)
“... a worker was seldom so much annoyed by what he got as by what he got in relation to his fellow workers.”
—Mary Barnett Gilson (1877–?)
““The ideal reasoner,” he remarked, “would, when he had once been shown a single fact in all its bearings, deduce from it not only all the chain of events which led up to it but also all the results which would follow from it.””
—Sir Arthur Conan Doyle (1859–1930)
“A new father quickly learns that his child invariably comes to the bathroom at precisely the times when he’s in there, as if he needed company. The only way for this father to be certain of bathroom privacy is to shave at the gas station.”
—Bill Cosby (20th century)
“The law hath not been dead, though it hath slept.”
—William Shakespeare (1564–1616)