Relation To The Ideal Gas Law
French physicist Émile Clapeyron combined Charles's law with Boyle's law in 1834 to produce a single statement which would become known as the ideal gas law. Claypeyron's original statement was:
where t is the Celsius temperature; and p0, V0 and t0 are the pressure, volume and temperature of a sample of gas under some standard state. The figure of 267 came directly from Gay-Lussac's work: the modern figure would be 273.15. For any given sample of gas, p0V0⁄267+t0 is a constant (Clapeyron denoted this constant R, and it is closely related to the modern gas constant); if the pressure is also constant, the equation simplifies to
as required.
The modern statement of the ideal gas law is:
where n is the amount of substance of the gas sample; and R is the gas constant. The amount of substance is constant for any given gas sample so, at constant pressure, the equation rearranges to:
where nR⁄p is the constant of proportionality.
An ideal gas is defined as a gas which obeys the ideal gas law, so Charles' law is only expected to be followed exactly by ideal gases. Nevertheless, it is a good approximation to the behaviour of real gases at relatively high temperatures and relatively low pressures.
Read more about this topic: Charles's Law
Famous quotes containing the words relation to the, relation to, relation, ideal, gas and/or law:
“Any relation to the land, the habit of tilling it, or mining it, or even hunting on it, generates the feeling of patriotism. He who keeps shop on it, or he who merely uses it as a support to his desk and ledger, or to his manufactory, values it less.”
—Ralph Waldo Emerson (1803–1882)
“Light is meaningful only in relation to darkness, and truth presupposes error. It is these mingled opposites which people our life, which make it pungent, intoxicating. We only exist in terms of this conflict, in the zone where black and white clash.”
—Louis Aragon (1897–1982)
“Art should exhilarate, and throw down the walls of circumstance on every side, awakening in the beholder the same sense of universal relation and power which the work evinced in the artist, and its highest effect is to make new artists.”
—Ralph Waldo Emerson (1803–1882)
“The ideal and the beautiful are identical; the ideal corresponds to the idea, and beauty to form; hence idea and substance are cognate.”
—Victor Hugo (1802–1885)
“Shielded, what sorts of life are stirring yet:
Legs lagged like drains, slippers soft as fungus,
The gas and grate, the old cold sour grey bed.”
—Philip Larkin (1922–1986)
“The law is equal before all of us; but we are not all equal before the law. Virtually there is one law for the rich and another for the poor, one law for the cunning and another for the simple, one law for the forceful and another for the feeble, one law for the ignorant and another for the learned, one law for the brave and another for the timid, and within family limits one law for the parent and no law at all for the child.”
—George Bernard Shaw (1856–1950)