Relation To The Ideal Gas Law
French physicist Émile Clapeyron combined Charles's law with Boyle's law in 1834 to produce a single statement which would become known as the ideal gas law. Claypeyron's original statement was:
where t is the Celsius temperature; and p0, V0 and t0 are the pressure, volume and temperature of a sample of gas under some standard state. The figure of 267 came directly from Gay-Lussac's work: the modern figure would be 273.15. For any given sample of gas, p0V0⁄267+t0 is a constant (Clapeyron denoted this constant R, and it is closely related to the modern gas constant); if the pressure is also constant, the equation simplifies to
as required.
The modern statement of the ideal gas law is:
where n is the amount of substance of the gas sample; and R is the gas constant. The amount of substance is constant for any given gas sample so, at constant pressure, the equation rearranges to:
where nR⁄p is the constant of proportionality.
An ideal gas is defined as a gas which obeys the ideal gas law, so Charles' law is only expected to be followed exactly by ideal gases. Nevertheless, it is a good approximation to the behaviour of real gases at relatively high temperatures and relatively low pressures.
Read more about this topic: Charles's Law
Famous quotes containing the words relation to, relation, ideal, gas and/or law:
“The proper study of mankind is man in his relation to his deity.”
—D.H. (David Herbert)
“The instincts of the ant are very unimportant, considered as the ant’s; but the moment a ray of relation is seen to extend from it to man, and the little drudge is seen to be a monitor, a little body with a mighty heart, then all its habits, even that said to be recently observed, that it never sleeps, become sublime.”
—Ralph Waldo Emerson (1803–1882)
“I’m no idealist to believe firmly in the integrity of our courts and in the jury system—that is no ideal to me, it is a living, working reality. Gentlemen, a court is no better than each man of you sitting before me on this jury. A court is only as sound as its jury, and a jury is only as sound as the men who make it up.”
—Harper Lee (b. 1926)
“... when I awake in the middle of the night, since I knew not where I was, I did not even know at first who I was; I only had in the first simplicity the feeling of existing as it must quiver in an animal.... I spent one second above the centuries of civilization, and the confused glimpse of the gas lamps, then of the shirts with turned-down collars, recomposed, little by little, the original lines of my self.”
—Marcel Proust (1871–1922)
“Macavity, Macavity, there’s no one like Macavity,
He’s broken every human law, he breaks the law of gravity.”
—T.S. (Thomas Stearns)