Relation To The Ideal Gas Law
French physicist Émile Clapeyron combined Charles's law with Boyle's law in 1834 to produce a single statement which would become known as the ideal gas law. Claypeyron's original statement was:
where t is the Celsius temperature; and p0, V0 and t0 are the pressure, volume and temperature of a sample of gas under some standard state. The figure of 267 came directly from Gay-Lussac's work: the modern figure would be 273.15. For any given sample of gas, p0V0⁄267+t0 is a constant (Clapeyron denoted this constant R, and it is closely related to the modern gas constant); if the pressure is also constant, the equation simplifies to
as required.
The modern statement of the ideal gas law is:
where n is the amount of substance of the gas sample; and R is the gas constant. The amount of substance is constant for any given gas sample so, at constant pressure, the equation rearranges to:
where nR⁄p is the constant of proportionality.
An ideal gas is defined as a gas which obeys the ideal gas law, so Charles' law is only expected to be followed exactly by ideal gases. Nevertheless, it is a good approximation to the behaviour of real gases at relatively high temperatures and relatively low pressures.
Read more about this topic: Charles's Law
Famous quotes containing the words relation to the, relation to, relation, ideal, gas and/or law:
“We must get back into relation, vivid and nourishing relation to the cosmos and the universe. The way is through daily ritual, and is an affair of the individual and the household, a ritual of dawn and noon and sunset, the ritual of the kindling fire and pouring water, the ritual of the first breath, and the last.”
—D.H. (David Herbert)
“You see, I am alive, I am alive
I stand in good relation to the earth
I stand in good relation to the gods
I stand in good relation to all that is beautiful
I stand in good relation to the daughter of Tsen-tainte
You see, I am alive, I am alive”
—N. Scott Momaday (b. 1934)
“The proper study of mankind is man in his relation to his deity.”
—D.H. (David Herbert)
“There is no dream of love, however ideal it may be, which does not end up with a fat, greedy baby hanging from the breast.”
—Charles Baudelaire (1821–1867)
“one pale woman all alone,
The daylight kissing her wan hair,
Loitered beneath the gas lamps’ flare,
With lips of flame and heart of stone.”
—Oscar Wilde (1854–1900)
“What, then, is the true Gospel of consistency? Change. Who is the really consistent man? The man who changes. Since change is the law of his being, he cannot be consistent if he stick in a rut.”
—Mark Twain [Samuel Langhorne Clemens] (1835–1910)