Calcium Sulfide - Reactivity and Uses

Reactivity and Uses

Calcium sulfide decomposes upon contact with water, including moist air, giving a mixture of Ca(SH)2, Ca(OH)2, and Ca(SH)(OH).

CaS + H2O → Ca(SH)(OH)
Ca(SH)(OH) + H2O → Ca(OH)2 + H2S

Milk of lime, Ca(OH)2, reacts with elemental sulfur to give a "lime-sulfur", which has been used as an insecticide. The active ingredient is probably a calcium polysulfide, not CaS.

It reacts with acids such as hydrochloric acid to release toxic hydrogen sulfide gas.

CaS + 2 HCl → CaCl2 + H2S

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