Production
CaS is produced by "carbothermic reduction" of calcium sulfate, which entails the conversion of carbon, usually as charcoal, to carbon dioxide:
- CaSO4 + 2 C → CaS + 2 CO2
and can react further:
- 3 CaSO4 + CaS → 4 CaO + 4 SO2
In the second reaction the sulfate (+6 oxidation state) oxidizes the sulfide (-2 oxidation state) to sulfur dioxide (+4 oxidation state), while it is being reduced to sulfur dioxide itself (+4 oxidation state).
CaS is also a byproduct in the Leblanc process.
Read more about this topic: Calcium Sulfide
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