Calcium Iodide - Reactions

Reactions

Henri Moissan first isolated pure calcium in 1898 by reducing calcium iodide with pure sodium metal:

CaI2 + 2 Na → 2 NaI + Ca

Calcium iodide can be formed by treating calcium carbonate, calcium oxide, or calcium hydroxide with hydroiodic acid:

CaCO3 + 2 HI → CaI2 + H2O + CO2

Calcium iodide slowly reacts with oxygen and carbon dioxide in the air, liberating iodine, which is responsible for the faint yellow color of impure samples.

2 CaI2 + 2 CO2 + O2 → 2 CaCO3 + 2 I2

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