Calcium Fluoride - Source of HF

Source of HF

Naturally occurring CaF2 is the principal source of hydrogen fluoride, a commodity chemical used to produce a wide range of materials. Hydrogen fluoride is liberated from the mineral by the action of concentrated sulfuric acid:

CaF2(s) + H2SO4 → CaSO4(solid) + 2 HF(g)

The resulting HF is converted into fluorine, fluorocarbons, and diverse fluoride materials. As of the late 1990s, five billion kilograms were mined annually.

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